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刘春元

暨南大学教授

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刘春元 2005年，哲学博士，Texas A&M University，导师，F. Albert Cotton (科顿)2005-2006年，博士后研究，Texas A&M University。2007年，同济大学化学学专业 ;2011-2016年，暨南大学生命科学技术学院化学系主任，2016-暨南大学化学与材料学院^[1]博士生导师。

中文名: 刘春元
国籍: 中国

性别: 男
职称: 暨南大学化学系教授

个人经历

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学击誉习经历：

1978–1981年：郴州师专，化学教整照育毕业。

1985–1988年：暨南大学化学系/中山大学，无机化学，硕士。

1999–2004年：美国Texas A&M大学化学系，导师，F. A. Cotton (科顿)，博士。

工连体永作经历：

1985–1996: 湘潭师范学院化学系，曾任副教授，省重点学科负责人，系主任。

1996–府禁赠1999: 美国堪萨斯大学化乘验厦学系Daryle H. Busch实验室，客座研究员。

2004–2006: Texas A&M大学化学系F. Albert. Cotton实验室，博士后研究。

2007–2011: 同济大学教授，博导。

20棵府牛12–: 暨南大学教授乘危邀，博导桨断桨驼。^[2]

研究兴趣

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分子电子器件

超分子组装与分子识别

仿生无机化学

近年论文

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主要论文：

1 .Optically Probing the Localized to Delocalized Transition in the Mo2-Mo2Mixed-valence Systems, Chem. Comm. 2017, 53, 3030-3033.

2.Study of asymmetrical mixed-valent Mo2-Mo2complexes in the class III regime，Suman Mallick, Dalton Trans, 2017, DOI: 10.1039/c6dt04915j, Tao Cheng, Miao Meng, Yu Yu Zhang and Chun Y. Liu,*

3.Photoinduced d electron transfer in phenylene bridged Mo2 dimers, Phys. Chem. Chem. Phys., 2017, 19, 1740-1745Tao Cheng, Xuan Xiao, Lei Zhang, Chun Y. Liu,* Li-Li Wang, Miao Meng, Fang Zhao, Hui Wang, Liang-Nian Ji。

4.Electronic Coupling between Two Covalently BondedDimolybdenum Units Bridged by a Naphthalene Group,Inorg. Chem.2016, 55, 6315–6322. Guang Yuan Zhu, Miao Meng, Ying Ning Tan, Xuan Xiao,Chun Y. Liu,*

5.Optical Determination of Electron Transfer Dynamics and Kinetics for Asymmetrical [Mo2]−ph−[Mo2] Systems, J. Phys. Chem. C,2016, 120, 12411−12422.Wei Yong Yu, Miao Meng, Hao Lei, Xue Dan He, and Chun Y. Liu,*

6.Tuning the Electronic Coupling and Electron Transfer in Mo2 Donor–Acceptor Systems by Variation of the Bridge Conformation Chem. Eur. J.2016, 22, 3115-3126.Mei Ting Kang, Miao Meng, Ying Ning Tan, Tao Cheng, Chun Y. Liu,*

7.Dimolybdenum dimers spaced by phenylene groups: The experimental models for study of electronic coupling,Inorg. Chim. Acta.2015424,. 63-74. Hao Lei, Xuan Xiao, Miao Meng, Tao Cheng, Yao Shu, Ying Ning Tan, Chun Y. Liu*,

8.Distinguishing the Strength of Electronic Coupling for Mo2-Containing Mixed-Valence Compounds within the Class III Regime, Chem. Eur. J. 2015, 21, 2353-2357. Tao Cheng, Ying Ning Tan, Yu Zhang, Yu Yu Zhang, Miao Meng, Hao Lei, Lu Chen, Chun Y. Liu*

9.Electronic Coupling in [Mo2]−Bridge−[Mo2] Systems with Twisted Bridges, Hong Li Zhang, Inorg. Chem. 2015, 54, 11314-11322. Guang Yuan Zhu, Gangyi Wang, Miao Meng, Chun Y. Liu,*Hao Lei.

10.Electronic Coupling and Electron Transfer between Two Dimolybdenum Units Spaced by a Biphenylene Group, J. Phys. Chem. C,2014, 118, 8308-8315. Xuan Xiao, Miao Meng, Hao Lei, Chun Y. Liu,*

11.Perturbation of the Charge Density between Two Bridged Mo2Centers: The Remote Substituent Effects, Inorg. Chem. 2014, 53, 9213−9221.Tao Cheng, Miao Meng, Hao Lei, andChun Y. Liu,*

12.Tuning the electronic coupling in Mo2–Mo2systems by variation of the coordinating atoms of the bridging ligands, Dalton Trans., 2014, 43, 14756–14765.Yao Shu,a Hao Lei, Ying Ning Tan, Miao Meng, Xiao Chun Zhang, Chun Y. Liu,*

13 “Spectroscopic Study of δ Electron Transfer between Two Covalently Bonded Dimolybdenum Units via a Conjugated Bridge: Adequate Complex Models to Test the Existing Theories for Electronic Coupling”, Chun Y. Liu,* Xuan Xiao, Miao Meng, Yu Zhang, and Mei Juan Han. J. Phys. Chem. C.2013 dx.doi.org/10.1021/jp406261w, Accepted.

14 “Abnormally Long-range Diamagnetic Anisotropy Induced by the Cyclic dp  Conjugation within a Six-membered Mo2/Chalcogen Ring”, Zhong Fei Tan, Chun Y. Liu*, Ziyun Li, Miao Meng and Ng Seik Weng, Inorg. Chem. 2012, 51, 2212

15 “Supramolecular assemblies of dimolybdenum transoids built by the Mo2-enhanced perfluorophenyl-perfluorophenyl synthons”, Li Juan Han, Li Yan Fan, Miao Meng, Xuefeng Wang and Chun Y. Liu*, Dalton Trans. 2011, 40，12832.

16 “Experimental and Theoretical Evidence of Aromatic Behavior in Heterobenzene-like Molecules having Metal-Metal Multiple Bonds”, Wenjuan Fang, Qiao He, Zhong Fei Tan, Chun Y. Liu,* Xin Lu,*and Carlos A. Murillo, Chemistry - A European Journal, 2011, 17, 10288.

17 “Enhanced Electronic Coupling in a Molecular Pair of Dimolybdenum Units Bridged by a Tetrathioterephthalate Dianion”, Mei Juan Han, Chun Y. Liu,* and Peng Fei Tian, Inorg. Chem. 2009, 48, 6347.

18 “Insertion of Ketenes into Lanthanocene n-Butylamide and Imidazolate Complexes” Ruiting Liu, Pengzhi Zheng, Linhong Weng, Xigeng Zhou* and Chun Y. Liu* J. Organomet. Chem. 2008, 693,1614.

19 “Enhancement in Electronic Communication upon Replacement of Mo–O by Mo–S Bonds in Tetranuclear Clusters of the Type [Mo2]2(μ-E—E)2, E = O or S” F. Albert Cotton, Zhong Li, Chun Y. Liu,* and Carlos A. Murillo,* Inorg. Chem. 2007, 46, 9294.

20 “Modulating Electronic Coupling Using O- and S-donor Linkers” F. Albert Cotton, Zhong Li, Chun Y. Liu,* Carlos A. Murillo,* Inorg. Chem. 2007, 46, 7840.

21 “A Deliberate Approach for the Syntheses of Heterometallic Suppramolecules Containing Dimolybdenum Mo24+ Species Coordinated to Metal Units” F. Albert Cotton, Zhong Li, Jia-Yi Jin, Chun Y. Liu,* Carlos, A. Murillo,* J. Chem. Soc., Dalton Trans., 2007, 2328.

22 “Electronic Localization versus Delocalization Determined by the Bonding of the Linker in an Isomer Pair” F. Albert Cotton,* Chun Y. Liu,* Carlos, A. Murillo,* Qinliang Zhao, Inorg. Chem. 2007, 46, 2604.

23 "A Fractional Bond Order of 1/2 in Pd25+Formamidinate Species; The Value of Very High Field EPR Spectra" John F. Berry,* Eckhard Bill, Eberhard Bothe, F. Albert Cotton,* Naresh S. Dalal,* Sergey A. Ibragimov, Narpinder Kaur, Chun Y. Liu, Carlos A. Murillo,* Saritha Nelluta, J. Micah North and Dino Villagrán, J. Am. Chem.Soc. 2007, 129, 1393.

24 “Molecular Pairs and A Propeller Containing Quadruply Bonded Dimolybdenum Units Linked by Polyamidate Ligands” F. Albert Cotton,* Zhong Li, Chun Y. Liu,* Carlos, A. Murillo,* Qinliang Zhao, Inorg. Chem. 2006, 45, 9795.

25 “An Isomeric Pair of Fluoride-Bridged Cyclic Dimolybdenum Triads” F. Albert Cotton,* Chun Y. Liu,* Carlos, A. Murillo,* Qinliang Zhao, Inorg. Chem. 2006, 45, 9480.

26 “Strong Electronic Communication by Direct Metal-metal Interaction in Molecules with Halide-Bridged Dimolybdenum Pairs” F. Albert Cotton,* Chun Y. Liu,* Carlos, A. Murillo,* Qingliang Zhao, Inorg. Chem. 2006, 45, 9493.

27 “Transition from a Nonbonding to a Bonding Interaction in a Tetranuclear [Mo2]2(µ-OR)4 Cluster” F. Albert Cotton,* Zhong Li, Chun Y. Liu, Carlos, A. Murillo,* Qingliang Zhao, Inorg. Chem. 2006, 45, 6387.

28 “Dimoylbdenum-Containing Molecular Triangles and Squares with Diamidate Linkers: Structural Diversity and Complexity” F. Albert Cotton,* Chun Y. Liu, Carlos, A. Murillo,* Xiaoping Wang, Inorg. Chem. 2006, 45, 2619.

29 “Strong Electronic Interaction between Two Dimolybdenum Units Linked by a Tetraazatetracene” F. Albert Cotton,* Zhong Li, Chun Y. Liu, Carlos, A. Murillo,* Inorg. Chem. 2006, 45, 767.

30 “Modeling Spin Interactions in a Cyclic Trimer and a Cuboidal Co4O4 Core with Co(II) In Tetrahedral and Octahedral Environments” John F. Berry, F. Albert Cotton,* Chun Y. Liu, Tongbu Lu, Carlos A. Murillo,* Boris S. Tsukerblat, Dino Villagrán and Xiaoping Wang, J. Am. Chem.Soc. 2005, 127, 4895.

31 “Strong Electronic Coupling between Dimolybdenum Units Linked by the N, N dimetheyl oxamidate Anion in a Molecule Having a Heteronaphthalene-like Structure.” F. Albert Cotton,* Chun Y. Liu, Carlos A. Murillo,* Dino Villagrán and Xiaoping Wang, J. Am. Chem. Soc, 2004, 126, 14822.

32 “Systematic Preparation of Mo24+ Building Blocks for Supramolecular Assemblies” F. Albert Cotton,* Chun Y. Liu and Carlos A. Murillo,* Inorg. Chem. 2004, 43, 2267.

33 “Fully Localized Mixed-Valence Oxidation Products of Molecules Containing Two Linked Dimolybdenum Units: An Effective Structural Criterion.” F. Albert Cotton,* Chun Y. Liu, Carlos A. Murillo* and Xiaoping Wang, J. Am. Chem. Soc, 2003, 125, 12945.

34 ”Modifying Electronic Communication in Dimolybdenum Units by Linkage Isomers of Bridged Oxamidate Dianions.” F. Albert Cotton,* Chun Y. Liu, Carlos A. Murillo,* Dino Villagrán and Xiaoping Wang, J. Am. Chem. Soc, 2003, 125, 13564.

35 ”Trapping Tetramethoxyzincate and -cobaltate(II) between Mo24+ Units.” F. A. Cotton,* Chun Y. Liu, Carlos A. Murillo and Xiaoping W, Inorg. Chem, 2003, 42, 4619.

36 “A Mixed-Valence Compound with One Unpaired Electron Delocalized over Four Molybdenum Atoms in A Cyclic Tetranuclear Ion.” F. A. Cotton,* Chun Y. Liu, Carlos A. Murillo* and Xiaoping Wang, Chem. Commun., 2003, 2190.

37 “How to Make a Major Shift in a Redox Potential: Ligand Control of the Oxidation State of Dimolybdenum Units.” F. Albert Cotton,* Lee M. Daniels, Chun Y. Liu, Carlos A. Murillo,* Arthur J. Schultz, and Xiaoping Wang, Inorg. Chem., 2002, 41, 4232.

38 “The First Designed Syntheses of Bis-dimetal Molecules in Which the Bridges Are Diamidate Ligands.” F. Albert Cotton,* Lee M. Daniels, James P. Donahue, Chun Y. Liu, and Carlos A. Murillo,* Inorg. Chem., 2002, 41, 1354.

39 “Steps on the Way to the First Dirhodium Tetracarboxylate with no Axial Ligand: Synthetic Lessons and a Plethora of Rh2(O2CR)4L2-n Compounds, n = 0, 1,2.” F. Albert Cotton,* Elizabeth A. Hillard, Chun Y. Liu, Carlos A. Murillo,* Wenning Wang and Xiaoping Wang, Inorg. Chim. Acta, 2002, 337, 233.^[3]